Electrogenerated Chemiluminescence. 60. Spectroscopic Properties and Electrogenerated Chemiluminescence of Decaphenylanthracene and Octaphenylnaphthalene.
نویسندگان
چکیده
منابع مشابه
Electrogenerated chemiluminescence 73: acid–base properties, electrochemistry, and electrogenerated chemiluminescence of neutral red in acetonitrile
We characterized the acid–base properties, electrochemistry, and electrogenerated chemiluminescence (ECL) of neutral red in acetonitrile (MeCN). To determine the acid–base properties, the basic form (NR) of neutral red was prepared and titrated with anhydrous HClO4, yielding pKa = 6.5 in MeCN. NR showed three irreversible electrochemical oxidations and a one-electron reversible reduction. Howev...
متن کاملElectrogenerated chemiluminescence. 58. Ligand-sensitized electrogenerated chemiluminescence in europium labels.
The electrochemistry and electrogenerated chemiluminescence (ECL) of a series of europium chelates, cryptates, and mixed-ligand chelate/cryptand complexes were studied. The complexes were of the following general forms: EuL(4)(-), where L = β-diketonate, a bis-chelating ligand (such as dibenzoylmethide), added as salts (A)EuL(4), where A = tetrabutylammonium ion or piperidinium ion (pipH(+)); ...
متن کاملDibenzotetraphenylperiflanthene: Synthesis, Photophysical Properties, and Electrogenerated Chemiluminescence
Fissure coupling of the fluoranthene adduct (7,12-diphenyl)benzo[k]fluoranthene (3) using AlCl3/NaCl, CoF3/TFA, or Tl(OCOCF3) gave the new polyaromatic hydrocarbon dibenzo{[f,f']-4,4',7,7'-tetraphenyl}diindeno[1,2,3-cd:1′,2′,3′-lm]perylene (4). Crystal data for 4: triclinic space group P1h, a ) 10.569(2) Å, b ) 11.565(4) Å, c ) 13.001(3) Å, R ) 95.05(2)°, â ) 111.24(1)°, γ ) 100.53(1)°, Z ) 1, ...
متن کاملElectrogenerated chemiluminescence from Au nanoclusters.
Electrogenerated chemiluminescence (ECL) of Au clusters is observed for the first time using triethyamine (TEA) as the coreactant. The potential application of ECL Au clusters in analytical chemistry is also demonstrated using Pb(2+) as an example.
متن کاملElectrogenerated Chemiluminescence 34 . Photo - Induced Electrogenerated Chemiluminescence and Up - Conversion at Semiconductor Electrodes
Photosensitized oxidations or reductions at pand n-type GaAs and InP semiconductor electrodes of aromatic species in aprotic solvents leading to electrogenerated chemiluminescence (ECL) are described. The energy of the irradiating light equal to the bandgap energy of the semiconductor and the electrical energy input couple to produce excited states which eventually produce emission at shorter w...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Acta Chemica Scandinavica
سال: 1998
ISSN: 0904-213X
DOI: 10.3891/acta.chem.scand.52-0045